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telluric acid : ウィキペディア英語版
telluric acid

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Telluric acid is a chemical compound with the formula Te(OH)6. It is a white solid made up of octahedral Te(OH)6 molecules which persist in aqueous solution. There are two forms, rhombohedral and monoclinic, and both contain octahedral Te(OH)6 molecules.
Telluric acid is a weak acid which is dibasic, forming tellurate salts with strong bases and hydrogen tellurate salts with weaker bases or upon hydrolysis of tellurates in water.〔〔Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. ISBN 0-12-352651-5.〕
==Preparation==
Telluric acid is formed by the oxidation of tellurium or tellurium dioxide with a powerful oxidising agent such as hydrogen peroxide, chromium trioxide or sodium peroxide.〔
:TeO2 + H2O2 + 2H2O → Te(OH)6
Crystallization of telluric acid solutions below 10 °C gives Te(OH)6.4H2O.〔
It is oxidizing, as shown by the electrode potential for the reaction below, although it is kinetically slow in its oxidations.〔
:H6TeO6 + 2H+ + 2e (unicode:⇌) TeO2 + 4H2O ''E''o = +1.02 V
Chlorine, by comparison, is +1.36V and selenous acid is +0.74V in oxidizing conditions.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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